Die effek van substituente in fosfien-ligande
Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie/South African Journal of Science and Technology
| Field | Value | |
| Title | Die effek van substituente in fosfien-ligande Substituent effects in phosphine ligands | |
| Creator | Renison, C. Alicia Williams, D. Bradley G. Muller, Alfred J. | |
| Description | Vorige studies het getoon dat die eienskappe van die P - atoom in PR₃ - sisteme sensitief is tenopsigte van veranderinge in sy chemiese omgewing (Miller 2010). Hierdie veranderinge wordmeegebring deur byvoorbeeld verandering van die substituent wat die steriese - en/of die elektroniese omgewing steur (Miller 2010). The study illustrates the use of the P-atom to evaluate steric and electronic effects in P-containing organic compounds. The work involves the synthesis of substituted triarylphosphines and their corresponding Rh Vaska complexes. High resolution X-ray crystallography, molecular modelling, 31P NMR spectroscopy and IR will be used to quantify substituent effects. | |
| Publisher | AOSIS | |
| Date | 2011-10-27 | |
| Identifier | 10.4102/satnt.v30i1.267 | |
| Source | Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie; Vol 30, No 1 (2011); 1 bladsy Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie; Vol 30, No 1 (2011); 1 bladsy 2222-4173 0254-3486 | |
| Language | eng | |
| Relation |
The following web links (URLs) may trigger a file download or direct you to an alternative webpage to gain access to a publication file format of the published article:
https://journals.satnt.aosis.co.za/index.php/satnt/article/view/267/307
https://journals.satnt.aosis.co.za/index.php/satnt/article/view/267/317
https://journals.satnt.aosis.co.za/index.php/satnt/article/view/267/308
https://journals.satnt.aosis.co.za/index.php/satnt/article/view/267/306
|
|
ADVERTISEMENT
